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Optical absorption from solvation-induced polarons on nanotubes

机译:纳米管上溶剂化诱导极化子的光吸收

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摘要

When an excess charge carrier is added to a one-dimensional (1D)semiconductor immersed in a polar solvent, the carrier can undergoself-localization into a large-radius adiabatic polaron. We explore the localoptical absorption from the ground state of 1D polarons using a simplifiedtheoretical model for small-diameter tubular structures. It is found that about90% of the absorption strength is contained in the transition to the secondlowest-energy localized electronic level formed in the polarization potentialwell, with the equilibrium transition energy larger than the binding energy ofthe polaron. Thermal fluctuations, however, cause a very substantial -- anorder of magnitude larger than the thermal energy -- broadening of thetransition. The resulting broad absorption feature may serve as a signature forthe optical detection of solvated charge carriers.
机译:当将过量的电荷载体添加到浸没在极性溶剂中的一维(1D)半导体中时,该载体可能会自我定位成大半径的绝热极化子。我们使用简化的理论模型,针对小直径管状结构,从一维极化子的基态探索局部光学吸收。发现在极化势阱中形成的向第二最低能量的局部电子能级的跃迁中包含约90%的吸收强度,平衡跃迁能量大于极化子的结合能。但是,热涨落会导致过渡过程非常严重(比热能大一个数量级)。所得的宽吸收特征可以用作溶剂化载流子的光学检测的特征。

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